热门关键词 :
举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.
选择ACS杂志名
Acc. Chem. Res.
ACS Appl. Mater. Interfaces
ACS Biomater. Sci. Eng.
ACS Catal.
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ACS Chem. Biol.
ACS Chem. Neurosci.
ACS Comb. Sci.
ACS Earth Space Chem.
ACS Energy Lett.
ACS Infect. Dis.
ACS Macro Lett.
ACS Med. Chem. Lett.
ACS Photonics
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Advances in Chemistry
Anal. Chem.
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Chem. Rev.
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Environ. Sci. Technol.
Environ. Sci. Technol. Lett.
Ind. Eng. Chem.
Ind. Eng. Chem. Res.
Ind. Eng. Chem., News Ed.
Inorg. Chem.
J. Am. Chem. Soc.
J. Agric. Food Chem.
J. Chem. Eng. Data
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J. Phys. Chem. Lett.
J. Proteome Res.
Macromolecules
Mol. Pharmaceutics
Nano Lett.
News Ed., Am. Chem. Soc
Org. Lett.
Org. Process Res. Dev.
Organometallics
选择RSC杂志名
Analytical Methods
Annual Reports on Analytical Atomic Spectroscopy ()
Biomaterials Science
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Food & Function
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Inorganic Chemistry Frontiers
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Journal of the Chemical Society, Dalton Transactions ()
Journal of the Chemical Society, Perkin Transactions 1 ()
Journal of the Chemical Society, Perkin Transactions 2, ()
Journal of the Chemical Society, Faraday Transactions
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases ()
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics ()
Journal of Environmental Monitoring ()
Journal of Materials Chemistry
Journal of Materials Chemistry A
Journal of Materials Chemistry B
Journal of Materials Chemistry C
Lab on a Chip
Materials Chemistry Frontiers
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Special Discussions of the Faraday Society ()
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Toxicology Research
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物理化学性质
1.435g/cm3
502?C at 760 mmHg
[ 中文名 ]:
[ 英文名 ]:
[中文别名 ]:
[英文别名 ]:
&物理化学性质
1.435g/cm3
502?C at 760 mmHg
[ 分子式 ]:
[ 分子量 ]:
[ 精确质量 ]:
[ 蒸汽压 ]:
1.06E-10mmHg at 25°C
[ 折射率 ]:
1.1 产品标识符
: 2-(3-Hydroxy-2-quinolyl)-1H-indene-1,3(2H)-dione
1.2 鉴别的其他方法
无数据资料
1.3 有关的确定了的物质或混合物的用途和建议不适合的用途
仅供科研用途，不作为药物、家庭备用药或其它用途。
模块2. 危险性概述
2.1 GHS分类
根据化学品全球统一分类与标签制度(GHS)的规定，不是危险物质或混合物。
2.3 其它危害物 - 无
模块3. 成分/组成信息
: C18H11NO3
: 289.29 g/mol
模块4. 急救措施
4.1 必要的急救措施描述
如果吸入,请将患者移到新鲜空气处。 如果停止了呼吸,给于人工呼吸。
用肥皂和大量的水冲洗。
用水冲洗眼睛作为预防措施。
切勿给失去知觉者从嘴里喂食任何东西。 用水漱口。
4.2 主要症状和影响，急性和迟发效应
4.3 及时的医疗处理和所需的特殊处理的说明和指示
无数据资料
模块5. 消防措施
5.1 灭火介质
灭火方法及灭火剂
用水雾,耐醇泡沫,干粉或二氧化碳灭火。
5.2 源于此物质或混合物的特别的危害
碳氧化物, 氮氧化物
5.3 给消防员的建议
如必要的话,戴自给式呼吸器去救火。
5.4 进一步信息
无数据资料
模块6. 泄露应急处理
6.1 人员的预防,防护设备和紧急处理程序
防止粉尘的生成。 防止吸入蒸汽、气雾或气体。
6.2 环境保护措施
不要让产物进入下水道。
6.3 抑制和清除溢出物的方法和材料
扫掉和铲掉。 存放进适当的闭口容器中待处理。
6.4 参考其他部分
丢弃处理请参阅第13节。
模块7. 操作处置与储存
7.1 安全操作的注意事项
在有粉尘生成的地方,提供合适的排风设备。一般性的防火保护措施。
7.2 安全储存的条件,包括任何不兼容性
贮存在阴凉处。 容器保持紧闭，储存在干燥通风处。
7.3 特定用途
无数据资料
模块8. 接触控制和个体防护
8.1 容许浓度
最高容许浓度
没有已知的国家规定的暴露极限。
8.2 暴露控制
适当的技术控制
常规的工业卫生操作。
个体防护设备
请使用经官方标准如NIOSH (美国) 或 EN 166(欧盟) 检测与批准的设备防护眼部。
戴手套取 手套在使用前必须受检查。
请使用合适的方法脱除手套(不要接触手套外部表面),避免任何皮肤部位接触此产品.
使用后请将被污染过的手套根据相关法律法规和有效的实验室规章程序谨慎处理. 请清洗并吹干双手
所选择的保护手套必须符合EU的89/686/EEC规定和从它衍生出来的EN 376标准。
根据危险物质的类型，浓度和量，以及特定的工作场所来选择人体保护措施。,
防护设备的类型必须根据特定工作场所中的危险物的浓度和含量来选择。
呼吸系统防护
不需要保护呼吸。如需防护粉尘损害，请使用N95型（US）或P1型（EN 143)防尘面具。
呼吸器使用经过测试并通过政府标准如NIOSH（US）或CEN（EU）的呼吸器和零件。
模块9. 理化特性
9.1 基本的理化特性的信息
a) 外观与性状
形状: 固体
无数据资料
c) 气味阈值
无数据资料
无数据资料
e) 熔点/凝固点
无数据资料
f) 起始沸点和沸程
无数据资料
无数据资料
h) 蒸发速率
无数据资料
i) 易燃性(固体,气体)
无数据资料
j) 高的/低的燃烧性或爆炸性限度 无数据资料
无数据资料
l) 蒸汽密度
无数据资料
m) 相对密度
无数据资料
无数据资料
o) n-辛醇/水分配系数
辛醇--水的分配系数的对数值: 2.812
p) 自燃温度
无数据资料
q) 分解温度
无数据资料
无数据资料
模块10. 稳定性和反应活性
10.1 反应性
无数据资料
10.2 稳定性
无数据资料
10.3 危险反应的可能性
无数据资料
10.4 应避免的条件
无数据资料
10.5 不兼容的材料
10.6 危险的分解产物
其它分解产物 - 无数据资料
模块11. 毒理学资料
11.1 毒理学影响的信息
无数据资料
皮肤刺激或腐蚀
无数据资料
眼睛刺激或腐蚀
无数据资料
呼吸道或皮肤过敏
无数据资料
生殖细胞突变性
无数据资料
此产品中没有大于或等于 0。1%含量的组分被 IARC鉴别为可能的或肯定的人类致癌物。
无数据资料
特异性靶器官系统毒性（一次接触）
无数据资料
特异性靶器官系统毒性（反复接触）
无数据资料
无数据资料
潜在的健康影响
吸入吸入可能有害。 可能引起呼吸道刺激。
摄入如服入是有害的。
皮肤如果通过皮肤吸收可能是有害的。 可能引起皮肤刺激。
眼睛可能引起眼睛刺激。
化学物质毒性作用登记: 无数据资料
模块12. 生态学资料
12.1 生态毒性
对鱼类的毒性半数致死浓度（LC50） - Pimephales promelas (黑头软口鲦鱼) - & 180 mg/l -
12.2 持久存留性和降解性
无数据资料
12.3 潜在的生物蓄积性
无数据资料
12.4 土壤中的迁移性
无数据资料
12.5 PBT 和 vPvB的结果评价
无数据资料
12.6 其它不利的影响
无数据资料
模块13. 废弃处置
13.1 废物处理方法
将剩余的和未回收的溶液交给处理公司。
受污染的容器和包装
作为未用过的产品弃置。
模块14. 运输信息
14.1 联合国危险货物编号
欧洲陆运危规: -国际海运危规: -国际空运危规: -
14.2 联合国（UN）规定的名称
欧洲陆运危规: 非危险货物
国际海运危规: 非危险货物
国际空运危规: 非危险货物
14.3 运输危险类别
欧洲陆运危规: -国际海运危规: -国际空运危规: -
14.4 包裹组
欧洲陆运危规: -国际海运危规: -国际空运危规: -
14.5 环境危险
欧洲陆运危规: 否国际海运危规 海运污染物: 否国际空运危规: 否
14.6 对使用者的特别提醒
无数据资料
模块 15 - 法规信息
模块16 - 其他信息
[ 海关编码 ]:
文献：I.G. Farbenind. Patent: DE619521 , 1932 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 767 Full Text Show Details Gen. Aniline Works Patent: US2006022 , 1933 ;
文献：I.G. Farbenind. Patent: DE619521 , 1932 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 767 Full Text Show Details Gen. Aniline Works Patent: US2006022 , 1933 ;
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[ 海关编码 ]:
生产厂家/供应商：
最新求购信息：
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相关化合物：热门关键词 :
举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.
选择ACS杂志名
Acc. Chem. Res.
ACS Appl. Mater. Interfaces
ACS Biomater. Sci. Eng.
ACS Catal.
ACS Cent. Sci.
ACS Chem. Biol.
ACS Chem. Neurosci.
ACS Comb. Sci.
ACS Earth Space Chem.
ACS Energy Lett.
ACS Infect. Dis.
ACS Macro Lett.
ACS Med. Chem. Lett.
ACS Photonics
ACS Sustainable Chem. Eng.
ACS Symposium Series
ACS Synth. Biol.
Advances in Chemistry
Anal. Chem.
Biochemistry
Bioconjugate Chem.
Biomacromolecules
Biotechnol. Prog.
C&EN Global Enterp
Chem. Res. Toxicol.
Chem. Rev.
Chem. Mater.
Crystal Growth & Design
Energy Fuels
Environ. Sci. Technol.
Environ. Sci. Technol. Lett.
Ind. Eng. Chem.
Ind. Eng. Chem. Res.
Ind. Eng. Chem., News Ed.
Inorg. Chem.
J. Am. Chem. Soc.
J. Agric. Food Chem.
J. Chem. Eng. Data
J. Chem. Educ.
J. Chem. Inf. Model.
J. Chem. Theory Comput.
J. Comb. Chem.
J. Med. Chem.
J. Nat. Prod.
J. Org. Chem.
J. Phys. Chem.
J. Phys. Chem. A
J. Phys. Chem. B
J. Phys. Chem. C
J. Phys. Chem. Lett.
J. Proteome Res.
Macromolecules
Mol. Pharmaceutics
Nano Lett.
News Ed., Am. Chem. Soc
Org. Lett.
Org. Process Res. Dev.
Organometallics
选择RSC杂志名
Analytical Methods
Annual Reports on Analytical Atomic Spectroscopy ()
Biomaterials Science
Catalysis Science & Technology
Chemical Communications
Chemical Communications (London) ()
Chemistry Education Research and Practice
Chemical Science
Chemical Society Reviews
Contemporary Organic Synthesis ()
CrysEngComm
Dalton Transactions
Discussions of the Faraday Society ()
Energy & Environmental Science
Environmental Science: Nano
Environmental Science: Processes & Impacts
Environmental Science: Water Research & Technology
Faraday Discussions
Faraday Discussions of the Chemical Society ()
Faraday Symposia of the Chemical Society ()
Faraday Special Discussions of the Chemical Society ()
Food & Function
Green Chemistry
Inorganic Chemistry Frontiers
Integrative Biology
Journal of Analytical Atomic Spectrometry
Journal of the Chemical Society, Chemical Communications ()
Journal of the Chemical Society D: Chemical Communications ()
Journal of the Chemical Society, Dalton Transactions ()
Journal of the Chemical Society, Perkin Transactions 1 ()
Journal of the Chemical Society, Perkin Transactions 2, ()
Journal of the Chemical Society, Faraday Transactions
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases ()
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics ()
Journal of Environmental Monitoring ()
Journal of Materials Chemistry
Journal of Materials Chemistry A
Journal of Materials Chemistry B
Journal of Materials Chemistry C
Lab on a Chip
Materials Chemistry Frontiers
Materials Horizons
MedChemComm
Metallomics
Molecular BioSystems
Molecular Systems Design & Engineering
Nanoscale Horizons
Natural Product Reports
New Journal of Chemistry
Organic & Biomolecular Chemistry
Organic Chemistry Frontiers
Photochemical & Photobiological Sciences
Physical Chemistry Chemical Physics
Polymer Chemistry
Quarterly Reviews, Chemical Society ()
Reaction Chemistry & Engineering
Royal Institute of Chemistry, Reviews ()
RSC Advances
Soft Matter
Special Discussions of the Faraday Society ()
Sustainable Energy & Fuels
Symposia of the Faraday Society ()
Toxicology Research
Transactions of the Faraday Society ()
物理化学性质
1.023g/cm3
302?C at 760mmHg
[ 中文名 ]:
[ 英文名 ]:
[英文别名 ]:
3-&(tert-butoxycarbonyl)amino&propionitrile
&物理化学性质
1.023g/cm3
302?C at 760mmHg
[ 分子式 ]:
[ 分子量 ]:
[ 精确质量 ]:
[ 折射率 ]:
Section 1 - Chemical Product
MSDS Name:tert-Butyl N-(2-cyanoethyl)carbamate 97% Material Safety Data Sheet
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Chemical Name
tert-Butyl N-(2-cyanoethyl)carbamate
Hazard Symbols: XN
Risk Phrases: 20/21/22
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
May cause eye irritation.
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# : Personal Protective Equipment Eyes: Not available.
Wear appropriate protective gloves to prevent skin exposure.
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR
or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Viscous liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H14N2O2
Molecular Weight: 170.21
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
LD50/LC50:
Not available.
Carcinogenicity:
tert-Butyl N-(2-cyanoethyl)carbamate - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
S 36/37 Wear suitable protective clothing and
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# : No information available.
None of the chemicals in this product are listed on the DSL/NDSL list.
is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
[ 危害码 (欧洲)
[ 风险声明 (欧洲) ]:
[ 安全声明 (欧洲) ]:
[ 海关编码 ]:
文献：ALMIRALL, S.A.; GRIMA POVEDA, Pedro M AGUILAR IZQUIERDO, N MIR CEPEDA, M CARRASCAL RIERA, M TERRICABRAS BELART, E GRACIA FERRER, J CASALS COLL, Gaspar Patent: WO A1, 2011 ; Location in patent: Page/Page column 71 ; WO
文献：B Hartke Archiv der Pharmazie, 1993 , vol. 326, # 5 p. 271 - 276
文献：H B Henichart Journal of Heterocyclic Chemistry, 1984 , vol. 21, # 3 p. 681 - 683
文献：US, ; US 5223516 A
文献：Drouet, F Fontaine, P Masson, G Zhu, Jieping Synthesis, 2009 , # 8 art. no. T19708SS, p. 1370 - 1374
文献：Synthesis, , # 3 p. 259 - 261
文献：Synthesis, , # 3 p. 259 - 261
文献：Angewandte Chemie - International Edition, , vol. 53, # 14 p. 3594 - 3598 Angew. Chem., , vol. 126, # 14 p. 3668 - 3672,5
文献：Angewandte Chemie - International Edition, , vol. 53, # 14 p. 3594 - 3598 Angew. Chem., , vol. 126, # 14 p. 3668 - 3672,5
文献：Angewandte Chemie - International Edition, , vol. 53, # 14 p. 3594 - 3598 Angew. Chem., , vol. 126, # 14 p. 3668 - 3672,5
文献：Angewandte Chemie - International Edition, , vol. 53, # 14 p. 3594 - 3598 Angew. Chem., , vol. 126, # 14 p. 3668 - 3672,5
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[ 海关编码 ]:
[ 中文概述 ]:
其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
[申报要素 ]:
品名, 成分含量, 用途
[ Summary ]:
HS: other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%
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